OIL OF TAXODIUM DISTICHUM
The
oil extracted from the wood of Taxodium distichum ("Southern Cypress")
by means of alcohol, has been examined by Odell.1 He fractionated the resinous
residue in vacuo and has thus isolated a hydrocarbon C15H24
which he calls cypressene ; it is an inodorous oily liquid, boiling-point
(35 mm.) 218° to 220° C., boiling-point (778 mm.) 295° to 300° C.; [α]20D
+ 6,53°. He has also extracted a compound C12 H20O, a bright
yellow oil with a strong odour, possessing the properties of an aldehyde; it
has received the name of cypral (boiling-point, 35 mm., 182° to 185°
G.); it is dextro-rotatory.
Cypressene
yields, on oxidation with nitric acid, an amorphous yellow product and an acid
possessing the odour of isovaleric acid; the amorphous product dissolves in
alkalies with a red coloration.
Odell
has also examined the oil from the cones of the same tree. When harvested in
September the cones yield 1 per cent, of a greenishyellow essential oil, with a
strong odour of pinene, w7hilst the cones harvested at a later period yield on
distillation 1’5 to 2 per cent, of a darker oil possessing an odour of lemon.
These two oils possess the following characters:
Specific
gravity 0,860 0,850
Optical
rotation +18° + 35° 30'
They
contain about 85 per cent, of D-α-pinene, 5 per cent, of D-limonene, and 2 per
cent, of an alcohol. Small amounts of carvone, and of a sesquiterpene, which is
probably cypressene, are also present.
0 Comment:
Post a Comment